You need a maxdrive or an xport to get your PS2 option file onto your pc.
If you have got a maxdrive you will have to convert the maxdrive option file to an xport file using "X-Port & Max Drive File Convertor" which you can download. Obviuosly if you have a X-port file you wont need to.
Also download "PESFan Editor 6"
Then using PESFan Editor 6 choose file/open & browse to your pc option file & open(can be any pc option file - default one or one you have downloaded.
then go to file/open op2 & browse to your X-port option file (PS2 file) & open that too.
Then go to tools/Convert OF2>OF1.
Then last of all save as - browse to your original pc file select it & save.
Put it in the right folder if not already.
My documents/Konami/Pro Evoltion Soccer 6/save/folder1
& Pronto you have a converted PS2 OF to PC OF.